Consider the following equilibrium in a closed container:

At a fixed temperature, the volume of the reaction container is halved. For this change, which of the given statements holds true regarding the equilibrium constant
and degree of dissociation (
)?
Text Solution
Verified by ExpertsD
For the reaction

where ' a ' is initial mole of
present in V litre and '
' is its degree of dissociation,
Also,
On reducing the volume of container to
, initial concentration of
becomes
. An increase in concentration leads to more dissociation of
in order to have
constant, a characteristic constant for a given reaction at a temperature.
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